(-)-Sparteine
CAS No. : 90-39-1
(Synonyms: (-)-Lupinidine)
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| Cat. No. : | HY-W012185 |
| M.Wt: | 234.39 |
| Formula: | C15H26N2 |
| Purity: | >98 % |
| Solubility: | H2O : 1.82 mg/mL (ultrasonic);DMSO : 12.5 mg/mL (ultrasonic) |
(-)-Sparteine ((-)-Lupinidine) is a chiral proton base and catalytic promoter. (-)-Sparteine promotes the enantioselective carbolithiation of cinnamyl derivatives with primary and secondary organolithium reagents. (-)-Sparteine forms mixed aggregates with lithium halides. As an exogenous chiral base, (-)-Sparteine deprotonates palladium-bound secondary alcohols, promotes the formation of palladium-alkoxide species, and alters the rate-limiting step of the catalytic cycle, thereby affecting reaction rate and enantioselectivity[1][2]. In Vitro:(-)-Sparteine promotes the enantioselective carbolithiation of various cinnamyl derivatives (including alcohol, ether, amine and homoallylic alcohol derivatives) with primary and secondary alkyllithiums[1].
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