BOP (hexafluorophosphate)
CAS No. : 56602-33-6
| Size | Price | Stock |
|---|---|---|
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| 50g | $19 | In-stock |
| 100g | $35 | In-stock |
| 500g | $135 | In-stock |
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| Cat. No. : | HY-Y0973 |
| M.Wt: | 442.28 |
| Formula: | C12H22F6N6OP2 |
| Purity: | >98 % |
| Solubility: | DMSO : 100 mg/mL (ultrasonic) |
BOP hexafluorophosphate is a phosphonium-type condensing agent. BOP hexafluorophosphate activates the carboxylic acid component to form a highly reactive O-benzotriazole ester (active ester) intermediate, which then reacts with the amino component to form an amide bond (peptide bond). BOP hexafluorophosphate is applicable to solid-phase polypeptide synthesis and nucleoside modification[1][2].
In Vitro:The racemization degree of Boc-His (Tos) is minimized when BOP hexafluorophosphate is used with equimolar diisopropylethylamine, and the epimer formation rate reaches approximately 3% upon excessive addition of diisopropylethylamine[1].
BOP hexafluorophosphate activates the amide functional group of silyl-protected pyrimidine nucleosides to generate in situ O4-(benzotriazol-1-yl) derivatives for C4 modification[2].
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