RuCl(p-cymene)[(R,R)-Ts-DPEN]


CAS No. : 192139-92-7

(Synonyms: RuCl[(R,R)-Tsdpen](p-cymene))

192139-92-7
Price and Availability of CAS No. : 192139-92-7
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250mg $20 In-stock
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Cat. No. : HY-W001069
M.Wt: 636.21
Formula: C31H35ClN2O2RuS
Purity: >98 %
Solubility: 10 mM in DMSO
Introduction of 192139-92-7 :

RuCl (p-cymene)[(R,R)-Ts-DPEN] (RuCl[(R,R)-Tsdpen](p-cymene)) is a Noyori-type chiral ruthenium asymmetric transfer hydrogenation catalyst. RuCl (p-cymene)[(R,R)-Ts-DPEN] is widely used in the asymmetric transfer hydrogenation and enantioselective reduction of ketones, imines and quinolines to construct specific stereoisomers with high optical purity[1][2]. In Vitro:RuCl(p-cymene)[(R,R)-Ts-DPEN] catalyzes asymmetric transfer hydrogenation of α-aryl-α,γ-dioxo-butyric acid esters, selectively reducing only the α-carbonyl group to form chiral α-hydroxy-γ-keto-butyric acid ethyl esters with ligand-matching (R,R) configuration, key building blocks for bioactive compounds including Croomycin, Citrafungins, and other natural extracts[2].

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